Power Generation Optimization of Reverse Electrodialysis: Effects of Key Operating and Design Parameters
DOI:
https://doi.org/10.46604/ijeti.2026.15684Keywords:
power generation, renewable energy, reverse electrodialysis, salinity gradient power, space velocityAbstract
Salinity gradient power (SGP) via reverse electrodialysis (RED) is a promising renewable energy source; however, maximizing efficiency requires balancing complex electrochemical and hydraulic variables. This study systematically investigates the effects of key operating and design parameters on RED power generation to improve energy efficiency. Laboratory-scale RED experiments are conducted by varying the concentrations of high-concentration (HC) and low-concentration (LC) NaCl solutions, space velocity, the number of ion-exchange membrane (IEM) pairs, and flow channel thickness. The results show that power density increases with concentration ratio and absolute solution concentration, with optimal performance achieved at HC concentrations of 1-2.5 M, LC concentrations of 0.02-0.05 M, and a concentration ratio above 50:1. An optimal space velocity of 0.25 1/min is identified. Increasing the number of IEM pairs enhances power density, while flow channel thicknesses of 1-2 mm minimize resistance. Under optimized conditions, a maximum power density of 0.446 W per square meter is achieved.
References
J. N. Weinstein and F. B. Leitz, “Electric Power from Differences in Salinity: The Dialytic Battery,” Science, vol. 191, no. 4227, pp. 557-559, 1976.
C. Simões, B. Vital, T. Sleutels, M. Saakes, and W. Brilman, “Scaled-Up Multistage Reverse Electrodialysis Pilot Study with Natural Waters,” Chemical Engineering Journal, vol. 450, part 4, article no. 138412, 2022.
J. Veerman, “Concepts and Misconceptions concerning the Influence of Divalent Ions on the Performance of Reverse Electrodialysis Using Natural Waters,” Membranes, vol. 13, no. 1, article no. 69, 2023.
A. Emdadi, L. F. Greenlee, and B. Logan, “Uphill Transport of Sulfate and Chloride Ions under Different Operational Conditions of a Reverse Electrodialysis (RED) Stack,” Chemical Engineering Journal, vol. 508, article no. 160897, 2025.
L. N. Nthunya, M. F. Bopape, O. T. Mahlangu, B. B. Mamba, B. Van der Bruggen, C. A. Quist-Jensen, et al., “Fouling, Performance and Cost Analysis of Membrane-Based Water Desalination Technologies: A Critical Review,” Journal of Environmental Management, vol. 301, article no. 113922, 2022.
S. K. Al Dawery, M. K. Al-Sawai, G. M. S. Al Muzami, S. H. K. Annamareddy, M. S. Al Dawari, R. H. Harharah, et al., “Treatment of Produced Water Using Prepared Activated Carbon-Based Sewage Sludge,” Separations, vol. 10, no. 10, article no. 519, 2023.
V. M. Ortiz-Martínez, L. Gómez-Coma, C. Tristán, G. Pérez, M. Fallanza, A. Ortiz, et al., “A Comprehensive Study on the Effects of Operation Variables on Reverse Electrodialysis Performance,” Desalination, vol. 482, article no. 114389, 2020.
J. Li, C. Zhang, Z. Wang, H. Wang, Z. Bai, and X. Kong, “Power Harvesting from Concentrated Seawater and Seawater by Reverse Electrodialysis,” Journal of Power Sources, vol. 530, article no. 231314, 2022.
T. Xu, “Ion Exchange Membranes: State of Their Development and Perspective,” Journal of Membrane Science, vol. 263, no. 1-2, pp. 1-29, 2005.
T. Sata, Ion Exchange Membranes: Preparation, Characterization, Modification and Application, 2nd ed., London: Royal Society of Chemistry, 2007.
D. A. Vermaas, M. Saakes, and K. Nijmeijer, “Doubled Power Density from Salinity Gradients at Reduced Intermembrane Distance,” Environmental Science & Technology, vol. 45, no. 16, pp. 7089-7095, 2011.
F. Helfer, C. Lemckert, and Y. G. Anissimov, “Osmotic Power with Pressure Retarded Osmosis: Theory, Performance and Trends – A Review,” Journal of Membrane Science, vol. 453, pp. 337-358, 2014.
E. Güler, R. Elizen, D. A. Vermaas, M. Saakes, and K. Nijmeijer, “Performance-Determining Membrane Properties in Reverse Electrodialysis,” Journal of Membrane Science, vol. 446, pp. 266-276, 2013.
E. Guler, Y. Zhang, M. Saakes, and K. Nijmeijer, “Tailor-Made Anion-Exchange Membranes for Salinity Gradient Power Generation Using Reverse Electrodialysis,” ChemSusChem, vol. 5, no. 11, pp. 2262-2270, 2012.
A. Ranade, K. Singh, A. Tamburini, G. Micale, and D. A. Vermaas, “Feasibility of Producing Electricity, Hydrogen, and Chlorine via Reverse Electrodialysis,” Environmental Science & Technology, vol. 56, no. 22, pp. 16062-16072, 2022.
T. F. Gül, M. Akalın, E. N. Dönmezler, A. Bolat, A. Cihanoğlu, E. Güler, et al., “Review on Reverse Electrodialysis Process-A Pioneering Technology for Energy Generation by Salinity Gradient,” Frontiers in Membrane Science and Technology, vol. 3, article no. 1414721, 2024.
Y. Mei and C. Y. Tang, “Co-Locating Reverse Electrodialysis with Reverse Osmosis Desalination: Synergies and Implications,” Journal of Membrane Science, vol. 539, pp. 305-312, 2017.
M. Sharma, P. P. Das, A. Chakraborty, and M. K. Purkait, “Clean Energy from Salinity Gradients Using Pressure Retarded Osmosis and Reverse Electrodialysis: A Review,” Sustainable Energy Technologies and Assessments, vol. 49, article no. 101687, 2022.
N. Y. Yip and M. Elimelech, “Thermodynamic and Energy Efficiency Analysis of Power Generation from Natural Salinity Gradients by Pressure Retarded Osmosis,” Environmental Science & Technology, vol. 46, no. 9, pp. 5230-5239, 2012.
D. A. Vermaas, J. Veerman, N. Y. Yip, M. Elimelech, M. Saakes, and K. Nijmeijer, “High Efficiency in Energy Generation from Salinity Gradients with Reverse Electrodialysis,” ACS Sustainable Chemistry & Engineering, vol. 1, no. 10, pp. 1295-1302, 2013.
J. W. Post, H. V. M. Hamelers, and C. J. N. Buisman, “Energy Recovery from Controlled Mixing Salt and Fresh Water with a Reverse Electrodialysis System,” Environmental Science & Technology, vol. 42, no. 15, pp. 5785-5790, 2008.
J. Veerman, J. W. Post, M. Saakes, S. J. Metz, and G. J. Harmsen, “Reducing Power Losses Caused by Ionic Shortcut Currents in Reverse Electrodialysis Stacks by a Validated Model,” Journal of Membrane Science, vol. 310, no. 1-2, pp. 418-430, 2008.
M. Tedesco, C. Scalici, D. Vaccari, A. Cipollina, A. Tamburini, and G. Micale, “Performance of the First Reverse Electrodialysis Pilot Plant for Power Production from Saline Waters and Concentrated Brines,” Journal of Membrane Science, vol. 500, pp. 33-45, 2016.
Y. Zhou, K. Zhao, C. Hu, H. Liu, Y. Wang, and J. Qu, “Electrochemical Oxidation of Ammonia Accompanied with Electricity Generation Based on Reverse Electrodialysis,” Electrochimica Acta, vol. 269, pp. 128-135, 2018.
X. Zhu, T. Kim, M. Rahimi, C. A. Gorski, and B. E. Logan, “Integrating Reverse-Electrodialysis Stacks with Flow Batteries for Improved Energy Recovery from Salinity Gradients and Energy Storage,” ChemSusChem, vol. 10, no. 4, pp. 797-803, 2017.
M. Tedesco, A. Cipollina, A. Tamburini, and G. Micale, “Towards 1 kw Power Production in a Reverse Electrodialysis Pilot Plant with Saline Waters and Concentrated Brines,” Journal of Membrane Science, vol. 522, pp. 226-236, 2017.
J. Moreno, N. de Hart, M. Saakes, and K. Nijmeijer, “CO2 Saturated Water As Two-Phase Flow for Fouling Control in Reverse Electrodialysis,” Water Research, vol. 125, pp. 23-31, 2017.
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