Carbon Dioxide Capture Performance of Mesostructured Adsorbent Impregnated with Polyethylenimine

Authors

  • Chien-Hung Chen Department of Chemistry, National Atomic Research Institute, Taoyuan, Taiwan, ROC
  • Ching-Tsung Yu Department of Chemistry, National Atomic Research Institute, Taoyuan, Taiwan, ROC
  • Yu-Fei Chang Department of Chemistry, National Atomic Research Institute, Taoyuan, Taiwan, ROC

DOI:

https://doi.org/10.46604/ijeti.2024.13298

Keywords:

polyethylenimine, CO2 capture, kinetic model, mesoporous materials

Abstract

This study aims to investigate the CO2 uptake performance of mesostructured adsorbents, such as Mobil Composition of Matter No. 41 (MCM-41), Santa Barbara Amorphous-15 (SBA-15), and multi-walled carbon nanotubes (MWNTs), modified with polyethylenimine (PEI). Mesoporous materials are loaded with 50 wt.% PEI using a wet impregnation method. CO2 kinetic experiments of the PEI-modified adsorbents are conducted by a thermogravimetric method. The results reveal that the CO2 adsorption capacities of the PEI/MCM-41, PEI/SBA-15, and PEI/MWNTs composites are 2.02, 3.06, and 2.93 mmol/g, respectively, under 15% CO2 flow at 348 K. The lower CO2 adsorption capacity of PEI/MCM-41 (2.02 mmol/g) is attributed to its poor porosity. The PEI/MWNTs composite has the fastest CO2 adsorption and desorption kinetics at the same temperature, compared to other PEI-modified adsorbents. These results suggest that MWNTs might play a significant “separator” role in effectively dispersing the PEI molecular chains on the mesostructured adsorbent.

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Published

2024-06-14

How to Cite

[1]
Chien-Hung Chen, Ching-Tsung Yu, and Yu-Fei Chang, “Carbon Dioxide Capture Performance of Mesostructured Adsorbent Impregnated with Polyethylenimine”, Int. j. eng. technol. innov., vol. 14, no. 3, pp. 298–308, Jun. 2024.

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